Vehicle electrification has attracted strong policy support in California due to its air-quality and climate benefits from adoption. However, it is unclear whether these benefits are equitable across the state’s sensitive populations and socioeconomic groups and whether disadvantaged communities are able to take advantage of the emission savings and associated health benefits of electric vehicle (EV) adoption. In this study, we analyze the statewide health impacts from the reduction of on-road emissions reduction (from reducing gasoline powered cars) and the increase in power plant emissions (from EV charging) across disadvantaged communities (DACs) detected by using the environmental justice screening tool CalEnviroScreen. The results indicate that EV adoption will reduce statewide primary PM2.5 emissions by 24.02-25.05 kilotonnes and CO2 emissions by 1,223-1,255 megatonnes through 2045, and the overall monetized emission-related health benefits from decreased mortality and morbidity can be 2.52-2.76 billion dollars overall. However, the average per capita per year air pollution benefit in DACs is about $1.60 lower than that in the least 10% vulnerable communities in 2020, and this disparity expands to over $31 per capita per year in 2045, indicating that the benefits overlook some of the state's most vulnerable population, and suggesting clear distributive and equity impacts of existing EV support policies. This study contributes to our growing understanding of environmental justice rising from vehicle electrification, underscoring the need for policy frameworks that create a more equitable transportation system.